Title of article
Aerobic oxidation of primary alcohols in the presence of activated secondary alcohols
Author/Authors
Egami، نويسنده , , Hiromichi and Shimizu، نويسنده , , Hideki and Katsuki، نويسنده , , Tsutomu، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
4
From page
783
To page
786
Abstract
Chemoselective aerobic oxidation of primary alcohols in the presence of activated secondary alcohols was effected under irradiation of visible light by using (nitrosyl)Ru(salen) complex 6 that possesses bulky 1-ethyl-1-methylpropyl groups at C3, C3′, C5 and C5′, as catalyst. For example, oxidation of n-decanol was >50 times faster than oxidation of 1-phenylethanol at 10 °C.
Keywords
Ru(salen) complex , Oxygen , Aerobic oxidation , Primary alcohol , aldehyde , Photo-irradation
Journal title
Tetrahedron Letters
Serial Year
2005
Journal title
Tetrahedron Letters
Record number
1844621
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