Title of article
Stereospecific and regioselective opening of an oxirane system. A new efficient entry to 1- or 3-monoacyl- and 1- or 3-monoalkyl-sn-glycerols
Author/Authors
Stamatov، نويسنده , , Stephan D. and Stawinski، نويسنده , , Jacek، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
5
From page
1601
To page
1605
Abstract
Acyl or alkyl glycidols in the presence of trifluoroacetic anhydride (TFAA) and trifluoroacetate anions, undergo a regioselective and stereospecific opening of the oxirane system to produce the bis(trifluoroacetylated) derivatives, from which the corresponding 1(3)-monoacyl-sn-glycerols or 1(3)-monoalkyl-sn-glycerols can be obtained directly in high purity (>99%) and in quantitative yields.
Keywords
1(3)-Monoacyl-sn-glycerols , 1(3)-Monoalkyl-sn-glycerols , Glycidyl oleate , 2-(Hexadecyloxymethyl)oxirane , Trifluoroacetic anhydride
Journal title
Tetrahedron Letters
Serial Year
2005
Journal title
Tetrahedron Letters
Record number
1844967
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