Title of article
Total synthesis of (±)-heliannuol C and E via aromatic Claisen rearrangement
Author/Authors
Vyvyan، نويسنده , , James R. and Oaksmith، نويسنده , , Jennifer M. and Parks، نويسنده , , Bevin W. and Peterson، نويسنده , , Elaine M.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
4
From page
2457
To page
2460
Abstract
The total synthesis of heliannuol C and E from a common intermediate are described. Key steps in the synthesis include a regioselective aromatic Claisen rearrangement to install the (1-vinyl)-4-methyl-3-pentenyl substituent and regioselective biomimetic 7-endo and 6-exo phenol epoxide cyclizations to form the cyclic ether moieties.
Keywords
Allelopathy , biomimetic reactions , epoxides , Oxygen heterocycles , Herbicides
Journal title
Tetrahedron Letters
Serial Year
2005
Journal title
Tetrahedron Letters
Record number
1845294
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