Title of article
Allylic oxidation: easy synthesis of alkenones from activated alkenes with TEMPO
Author/Authors
Breton، نويسنده , , Tony and Liaigre، نويسنده , , Denis and Belgsir، نويسنده , , El Mustapha، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
4
From page
2487
To page
2490
Abstract
Activated alkenes and dienes are converted into the corresponding alkenone in excellent yields (>90%). In aqueous acetonitrile, the transformations are catalyzed by 2,2,6,6-tetramethyl-1-oxopiperidinium (TEMPO+) in the presence of water and 2,6-lutidine. TEMPO+ cations were regenerated electrochemically from the radical parent (TEMPO) at a vitreous carbon anode.
Keywords
Oxidation , Electrosynthesis , TEMPO
Journal title
Tetrahedron Letters
Serial Year
2005
Journal title
Tetrahedron Letters
Record number
1845306
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