Title of article
Palladium(II)-catalyzed ring expansion of a 1-alkenyl cyclopentanol
Author/Authors
Garcيa Martيnez، نويسنده , , Antonio and Teso Vilar، نويسنده , , Enrique and Garcيa Fraile، نويسنده , , Amelia and de la Moya Cerero، نويسنده , , Santiago and Lora Maroto، نويسنده , , Beatriz، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
3
From page
3509
To page
3511
Abstract
7,7-Dimethyl-2-methylenenorbornan-1-ol, a strained bicyclic 1-alkenyl cyclopentanol, undergoes Wagner–Meerwein rearrangement to fenchone under treatment with a catalytic amount of PdCl2(PPh3)2 in refluxing N-methylpyrrolidin-2-one. The described reaction constitutes the first example of the palladium(II)-catalyzed ring expansion of 1-alkenyl cyclopentanols to the corresponding cyclohexanones.
Keywords
Ring expansion , Bicycles , Cyclopentanols , Palladium catalysis
Journal title
Tetrahedron Letters
Serial Year
2005
Journal title
Tetrahedron Letters
Record number
1845656
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