Title of article
Anion nucleophilicity in ionic liquids: a comparison with traditional molecular solvents of different polarity
Author/Authors
Landini، نويسنده , , Dario and Maia، نويسنده , , Angelamaria، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
3
From page
3961
To page
3963
Abstract
The nucleophilic reactivity of a homogeneous series of anions (halides, pseudohalides and organic anions) in the ionic liquids [hexmim] [ClO4] and [hexmim] [PF6] has been measured in their reaction with n-alkyl methanesulfonates, and compared with that found in traditional molecular solvents of different polarity, that is, chlorobenzene, DMSO, and MeOH.
Keywords
Nucleophilic substitutions , Anion reactivity , Water effect , Ionic liquids , Hydrogen bonding effect
Journal title
Tetrahedron Letters
Serial Year
2005
Journal title
Tetrahedron Letters
Record number
1845843
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