Title of article
Stereoselective synthesis of (E)-1-iodo-1-selenoalkenes via hydroalumination–iodination of 1-alkynyl selenides
Author/Authors
Carlos Pérez-Balado، نويسنده , , Carlos and Lucaccioni، نويسنده , , Fabio and Markَ، نويسنده , , Istvلn E.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
4
From page
4883
To page
4886
Abstract
syn-Hydroalumination of 2,4,6-triisopropylphenylselanyl-1-alkynes 22 with DIBAL-H, followed by Al/I exchange with I2, afforded selectively the corresponding (E)-1-iodo-1-selenoalkenes in good yields. The sterically hindered 2,4,6-triisopropylphenyl group proved to be mandatory and prevented the formation of undesired by-products.
Keywords
Hydroalumination , 4 , 6-Triisopropylphenyl selenide , 2 , iodination , Selenides
Journal title
Tetrahedron Letters
Serial Year
2005
Journal title
Tetrahedron Letters
Record number
1846169
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