Title of article
Palladium-catalyzed allylic alkylation of optically active α-alkenyl-α-acyloxytrialkylsilane
Author/Authors
Sakaguchi، نويسنده , , Kazuhiko and Yamada، نويسنده , , Takeshi and Ohfune، نويسنده , , Yasufumi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
4
From page
5009
To page
5012
Abstract
Pd-catalyzed inter- and intramolecular allylic alkylations of optically active α-alkenyl-α-acyloxysilanes are described. The reactions proceeded in a regio- and stereoselective manner to give the corresponding (E)-vinylsilanes in which the ee of the starting material was completely transferred to the product.
Keywords
Pd-catalyzed allylic alkylation , ?-Acyloxysilane , chirality transfer , ?-Silyl cation
Journal title
Tetrahedron Letters
Serial Year
2005
Journal title
Tetrahedron Letters
Record number
1846211
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