Title of article
The highly enantioselective Diels–Alder reaction of 1,2-dihydropyridine using chiral cationic palladium–phosphinooxazolidine catalyst for the synthesis of chiral isoquinuclidines
Author/Authors
Nakano، نويسنده , , Hiroto and Tsugawa، نويسنده , , Natsumi and Fujita، نويسنده , , Reiko، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
5
From page
5677
To page
5681
Abstract
The enantioselective Diels–Alder reactions of 1-phenoxycarbonyl-1,2-dihydropyridine with 1-alkylated acryloyl-pyrazolidin-3-ones using chiral cationic palladium–phosphinooxazolidine (Pd–POZ) catalyst afforded chiral isoquinuclidines with excellent enantioselectivity (up to 97% ee).
Keywords
1 , 2-dihydropyridine , Chiral isoquinuclidines , enantioselective Diels–Alder reaction , Chiral cationic palladium–phosphinooxazolidine catalyst
Journal title
Tetrahedron Letters
Serial Year
2005
Journal title
Tetrahedron Letters
Record number
1846450
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