Title of article
Palladium-catalyzed construction of amino acid derivatives possessing vicinal chiral quaternary and tertiary carbon centers at the α and β positions
Author/Authors
Ikeda، نويسنده , , Daiji and Kawatsura، نويسنده , , Motoi and Uenishi، نويسنده , , Junichi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
4
From page
6663
To page
6666
Abstract
The palladium catalyzed regio- and diastereo-selective allylic alkylation of (R)-2-acetoxy-4-aryl-3-butene with N-(diphenylmethylidene)glycinate and N-(diphenylmethylidene)alaninate occurred. The stereochemistry was controlled by the use of o-(diphenylphosphino)carboxylic acid, and produced new amino acid derivatives possessing vicinal chiral quaternary and tertiary carbon centers at the α and β positions.
Keywords
Vicinal chiral carbon centers , Amino acids derivatives , Pd-catalyzed allylic alkylation , Regio- and diastereo-selectivity
Journal title
Tetrahedron Letters
Serial Year
2005
Journal title
Tetrahedron Letters
Record number
1846726
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