Title of article
Probing the conformational changes upon oxidation in cross-conjugated architectures featuring vinylogous TTF units
Author/Authors
Berridge، نويسنده , , Rory and Skabara، نويسنده , , Peter J. and Andreu، نويسنده , , Raquel and Garيn، نويسنده , , Javier and Orduna، نويسنده , , Jesْs and Torra، نويسنده , , Marta، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2005
Pages
5
From page
7871
To page
7875
Abstract
We report the synthesis and electropolymerisation of 1,3,5-tris(1,3-dithiole-2-ylidenephenylene)benzene 4. The resulting polymer features extended tetrathiafulvalene (TTF) units and can be considered as a cross-conjugated, cross-linked structure. Upon p-doping, electrochemical and UV–vis spectroelectrochemical experiments indicate that the polymer undergoes a unique conformational change within the dendralene unit from one definitive orthogonal arrangement to another.
Keywords
Dendralenes , TTF , Polymers
Journal title
Tetrahedron Letters
Serial Year
2005
Journal title
Tetrahedron Letters
Record number
1847295
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