Title of article
N-Hydroxy indoles as flexible substrates in rearrangements—a novel reaction with activated triple bonds
Author/Authors
Duarte، نويسنده , , Mariana P. and Mendonça، نويسنده , , Ricardo F. and Prabhakar، نويسنده , , Sundaresan and Lobo، نويسنده , , Ana M.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2006
Pages
4
From page
1173
To page
1176
Abstract
A novel rearrangement of N-hydroxy indole derivatives obtained from addition of N-hydroxy indoles to the activated triple bonds of alkynes was found to coexist with 3,3-sigmatropic rearrangements to the indolic ring. A mechanism involving an intermediate oxaziridinium ring rationalizes the transformation.
Keywords
N-Hydroxy indoles , Rearrangements , additions , Oxaziridinium
Journal title
Tetrahedron Letters
Serial Year
2006
Journal title
Tetrahedron Letters
Record number
1848830
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