Title of article
Direct ring functionalisation of 1,4,7-trimethyl-1,4,7-triazacyclononane and its application in the preparation of functional [L2Mn2O3]-type complexes
Author/Authors
Koek، نويسنده , , Jean H. and Kohlen، نويسنده , , Erik W.J.M.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2006
Pages
3
From page
3673
To page
3675
Abstract
Treatment of 1,4,7-trimethyl-1,4,7-triazacyclononane (metacn) with N-bromosuccinimide (NBS) gave a bicyclic ammonium intermediate, which was ring-opened to 2-cyano-1,4,7-trimethyl-1,4,7-triazacyclononane by reaction with potassium cyanide. Reduction to the amine followed by reaction with anhydrides gave amides, which could subsequently be converted to dinuclear tris-μ-oxo manganese complexes.
Keywords
N-ligands , Manganese , Macrocyclic ligands , Amines , Oxidation , Synthetic methods
Journal title
Tetrahedron Letters
Serial Year
2006
Journal title
Tetrahedron Letters
Record number
1850420
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