• Title of article

    Enantioselective olefin epoxidation using homologous amine and iminium catalysts—a direct comparison

  • Author/Authors

    Gonçalves، نويسنده , , Maria Helena and Martinez، نويسنده , , Alexandre and Grass، نويسنده , , Stéphane and Page، نويسنده , , Philip C. Bulman and Lacour، نويسنده , , Jérôme، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2006
  • Pages
    5
  • From page
    5297
  • To page
    5301
  • Abstract
    Homologous biphenyl and (diastereomeric) binaphthyl tertiary azepines and quaternary iminium salts were prepared from (+)-(S,S)-l-acetonamine. Both the amines and iminium ions behave as effective catalysts for the enantioselective epoxidation of unfunctionalized olefins (ee up to 83%).
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2006
  • Journal title
    Tetrahedron Letters
  • Record number

    1851448