Title of article
Reactivity of per-O-acetylated 1-thioglycosides and glycosyl sulfones towards chromium(II) complexes in aqueous medium
Author/Authors
Micskei، نويسنده , , K?roly and Juh?sz، نويسنده , , Zsuzsa and Ratkovi?، نويسنده , , Zoran R. and Soms?k، نويسنده , , L?szl?، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2006
Pages
4
From page
6117
To page
6120
Abstract
Anomeric carbon–sulfur bonds in 1-thioglycosides and glycosyl sulfones can be cleaved by chromium(II) complexes in water–DMF medium. Anomeric radicals as well as sugar–chromium(III) complex intermediates can be generated in these reactions, leading in some cases, to the exclusive formation of the corresponding glycals.
Journal title
Tetrahedron Letters
Serial Year
2006
Journal title
Tetrahedron Letters
Record number
1852089
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