Title of article
A facile and efficient synthesis of aryltriethoxysilanes via sonochemical Barbier-type reaction
Author/Authors
Lee، نويسنده , , Adam Shih-Yuan and Chang، نويسنده , , Yu-Ting and Chu، نويسنده , , Shu-Fang and Tsao، نويسنده , , Kuo-Wei، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2006
Pages
3
From page
7085
To page
7087
Abstract
A series of aryltriethoxysilanes was synthesized from the reaction mixture of aryl bromide, Mg powder, 1,2-dibromoethane and tetraethyl orthosilicate in THF under ultrasound. This sonochemical Barbier-type reaction provides a simple and efficient method for preparation of aryltriethoxysilanes. The Hiyama cross-coupling reaction of phenyltriethoxysilane with bromobenzene was investigated under different palladium catalysts and Pd(PhCN)2Cl2 was found to be the best choice.
Journal title
Tetrahedron Letters
Serial Year
2006
Journal title
Tetrahedron Letters
Record number
1852627
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