Title of article
Rhodium-catalyzed silylation of ortho-functionalized aryl halides with hydrosilanes
Author/Authors
Yamanoi، نويسنده , , Yoshinori and Nishihara، نويسنده , , Hiroshi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2006
Pages
5
From page
7157
To page
7161
Abstract
The silylation of ortho-functionalized aryl iodide with trialkylsilanes in the presence of RhCl(CO)(PPh3)2 or [Rh(cod)2]BF4 and K3PO4 provides the corresponding arylalkylsilane in good to high yield. This catalytic system showed a dramatically different activity when Pd(t-Bu3P)2 was used as a catalyst.
Journal title
Tetrahedron Letters
Serial Year
2006
Journal title
Tetrahedron Letters
Record number
1852674
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