Title of article
A novel photoinduced ring opening and isomerization of adamantane-2-spiro isoxazolines using Mo(CO)6
Author/Authors
Senthilvelan، نويسنده , , Annamalai and Lee، نويسنده , , Gene-Hsiang and Chung، نويسنده , , Wen-Sheng، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2006
Pages
5
From page
7179
To page
7183
Abstract
The Mo(CO)6-mediated photoinduced ring-opening reactions of adamantane isoxazolines involve novel rearrangement that provide enaminoketones as major products and β-hydroxy ketones as minor ones; in contrast, only β-hydroxy ketones and α,β-unsaturated ketones were obtained under thermal condition.
Keywords
Adamantane isoxazolines , photorearrangement , Enaminoketones , Isomerization
Journal title
Tetrahedron Letters
Serial Year
2006
Journal title
Tetrahedron Letters
Record number
1852684
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