Title of article
Free radical bromination by the H2O2–HBr system on water
Author/Authors
Podgor?ek، نويسنده , , Ajda and Stavber، نويسنده , , Stojan and Zupan، نويسنده , , Marko and Iskra، نويسنده , , Jernej، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2006
Pages
3
From page
7245
To page
7247
Abstract
An aqueous solution of hydrogen peroxide and hydrogen bromide illuminated by a 40 W incandescent light bulb serves as a source of bromine radicals. Various substituted toluenes (H, Me, tBu, Br, COOEt, COPh, NO2) were brominated at the benzyl position. This haloperoxidase-like system for benzylic bromination does not require the presence of metal ions or an organic solvent for efficient conversion of methyl-arenes to benzyl bromides.
Keywords
Bromination , radicals , haloperoxidase , green chemistry , Hydrogen peroxide , Benzyl bromination , Halogenation , water
Journal title
Tetrahedron Letters
Serial Year
2006
Journal title
Tetrahedron Letters
Record number
1852714
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