Title of article
Preparation and structural characterization of a new class of stable thioketones: ortho-hydroxythioacetophenones
Author/Authors
Nguyen، نويسنده , , Trung Thanh and Le، نويسنده , , Thach Ngoc and Hansen، نويسنده , , Poul Erik and Duus، نويسنده , , Fritz، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2006
Pages
3
From page
8433
To page
8435
Abstract
ortho-Hydroxythioacetophenone and four structurally related ortho-hydroxyaryl methyl thioketones have been prepared from the corresponding ketones by reaction with gaseous H2S and HCl in ethanol under strictly controlled reaction conditions. The remarkable stability of the new monomeric thioketones seems to be due to a strong intramolecular O–H⋯SC hydrogen bonding.
Keywords
Thioketone synthesis , ?-Hydroxythioketones , intramolecular hydrogen bonding
Journal title
Tetrahedron Letters
Serial Year
2006
Journal title
Tetrahedron Letters
Record number
1853330
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