• Title of article

    Preparation and structural characterization of a new class of stable thioketones: ortho-hydroxythioacetophenones

  • Author/Authors

    Nguyen، نويسنده , , Trung Thanh and Le، نويسنده , , Thach Ngoc and Hansen، نويسنده , , Poul Erik and Duus، نويسنده , , Fritz، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2006
  • Pages
    3
  • From page
    8433
  • To page
    8435
  • Abstract
    ortho-Hydroxythioacetophenone and four structurally related ortho-hydroxyaryl methyl thioketones have been prepared from the corresponding ketones by reaction with gaseous H2S and HCl in ethanol under strictly controlled reaction conditions. The remarkable stability of the new monomeric thioketones seems to be due to a strong intramolecular O–H⋯SC hydrogen bonding.
  • Keywords
    Thioketone synthesis , ?-Hydroxythioketones , intramolecular hydrogen bonding
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2006
  • Journal title
    Tetrahedron Letters
  • Record number

    1853330