Title of article
Chloride ion promoted nucleophilic pentafluorophenylation of imines
Author/Authors
Levin، نويسنده , , Vitalij V. and Dilman، نويسنده , , Alexander D. and Belyakov، نويسنده , , Pavel A. and Struchkova، نويسنده , , Marina I. and Tartakovsky، نويسنده , , Vladimir A.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2006
Pages
5
From page
8959
To page
8963
Abstract
Nucleophilic addition of the pentafluorophenyl group from (C6F5)3SiF to non-activated imines affording α-C6F5-substituted secondary amines in high yield has been described. The reaction proceeds via simultaneous activation of imines and the silane reagent by means of a proton and chloride ion, respectively.
Keywords
hypervalent silicon , Fluorinated silanes , imines
Journal title
Tetrahedron Letters
Serial Year
2006
Journal title
Tetrahedron Letters
Record number
1853597
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