Title of article
Application of intramolecular Dِtz reaction to the synthesis of ansa-compounds: concise synthesis of arnebinol
Author/Authors
Watanabe، نويسنده , , Masahito and Tanaka، نويسنده , , Kyosuke and Saikawa، نويسنده , , Yoko and Nakata، نويسنده , , Masaya، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
4
From page
203
To page
206
Abstract
Fischer carbene complexes having long alkynyloxy chains regioselectively produced oxametacyclophanes via the intramolecular Dِtz reaction. The utility of this reaction was demonstrated in the synthesis of arnebinol, an ansa-type terpenoid, from geranyl acetate in six steps.
Keywords
Dِtz reaction , Ansa-compound , Fischer carbene complex , Arnebinol
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1853882
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