Title of article
Porphyrenediynes: synthesis and cyclization of meso-enediynylporphyrins
Author/Authors
Spence، نويسنده , , John D. and Hargrove، نويسنده , , Amanda E. and Crampton، نويسنده , , Hannah L. and Thomas، نويسنده , , David W.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
4
From page
725
To page
728
Abstract
Synthetic methodology to prepare porphyrinylethynyl enediynes has been developed. Compared to phenylethynyl derivatives, a bulky porphyrinic substituent on the alkyne significantly increases the thermal barrier toward Bergman cyclization and leads to multiple photolysis products.
Keywords
Enediynes , Bergman cyclization , Porphyrins
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1854052
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