Title of article
Oxidative entry to α-oxy N-acyl aminals and hemiaminals: efficient formation of 2-(N-acylaminal) substituted tetrahydropyrans
Author/Authors
Huang، نويسنده , , Xianhai and Shao، نويسنده , , Ning and Palani، نويسنده , , Anandan and Aslanian، نويسنده , , Robert، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
5
From page
1967
To page
1971
Abstract
An efficient new method to synthesize α-oxy N-acyl aminals and hemiaminals in a single step from readily synthesized N-acyl enamines has been developed using PhI(OAc)2 as the oxidant. The reaction conditions are very mild and the products are obtained in good yields (65–92%). A possible mechanistic pathway is laid out.
Keywords
N-Acyl enamines , ?-Oxy N-acyl aminals and hemiaminals , (Diacetoxyiodo)benzene
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1854468
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