Title of article
Hydrosilylation and double silylation of carbonyl compounds with 1,1′-bis(dimethylsilyl)ferrocene using nickel- and platinum-catalysts
Author/Authors
Kong، نويسنده , , Young Kun and Kim، نويسنده , , Jinsik and Choi، نويسنده , , Sungkeun and Choi، نويسنده , , Seok-Bong، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
4
From page
2033
To page
2036
Abstract
A series of ferrocene-based organosilicon compounds have been prepared via hydrosilylation or double silylation of carbonyl compounds with 1,1′-bis(dimethylsilyl)ferrocene using (C2H4)Pt(PPh3)2 or Ni(PEt3)4 catalysts. In general, while the platinum catalyst (C2H4)Pt(PPh3)2 preferentially produced cyclic double-silylated products, the Ni(PEt3)4 catalyst led to the hydrosilylated ferrocene products from aldehydes or ketones.
Keywords
Hydrosilylation , Catalyst , silane , Ferrocene , Dehydrogenative double silylation
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1854497
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