Title of article
A novel method for regioselective ring-opening reduction of 4,6-O-benzylidene hexopyranoside derivatives using CoCl2 and BH3·THF
Author/Authors
Tani، نويسنده , , Shinki and Sawadi، نويسنده , , Sho and Kojima، نويسنده , , Masaru and Akai، نويسنده , , Shoji and Sato، نويسنده , , Ken-ichi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
2
From page
3103
To page
3104
Abstract
A novel and facile reductive ring-opening reaction for 4,6-O-benzylidene acetal derivatives of hexopyranosides using CoCl2/BH3·THF gave the corresponding 4-O-benzyl-6-OH derivatives selectively in good yields. This convenient method should allow large-scale synthesis at low cost.
Keywords
carbohydrates , Borane , Reductive benzylidene ring-opening , cobalt chloride
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1854840
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