Title of article
An expedient stereoselective synthesis of (Z)- and (E)-allyl iodides from Baylis–Hillman adducts along with selective iodination of benzylic alcohols using the polymethylhydrosiloxane–iodine system
Author/Authors
Das، نويسنده , , Biswanath and Holla، نويسنده , , Harish and Srinivas، نويسنده , , Yallamalla and Chowdhury، نويسنده , , Nikhil and Bandgar، نويسنده , , B.P.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
4
From page
3201
To page
3204
Abstract
A stereoselective method has been developed for the synthesis of (Z)- and (E)-allyl iodides from Baylis–Hillman adducts using polymethylhydrosiloxane (PMHS) and iodine in chloroform at room temperature. In addition, the reagent system has been utilized for the iodination of benzylic alcohols selectively.
Keywords
Baylis–Hillman adduct , Polymethylhydrosiloxane (PMHS) , (Z)- and (E)-allyl iodides , iodine , Benzylic iodide
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1854871
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