Title of article
Substituent effects in addition of iodine thiocyanate to alkenes
Author/Authors
Brammer، نويسنده , , Christopher N. and Nelson، نويسنده , , Donna J. and Li، نويسنده , , Ruibo، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
5
From page
3237
To page
3241
Abstract
The plots of logarithms of relative rates of ISCN addition to alkenes versus alkene IPs and versus alkene HOMO energies reveal that the alkene relative reactivity depends upon both electronic and steric effects of the substituents. Steric effects are related not only to the degree of substitution on the CC bond but also to the relative position, size, and branching of alkyl substituents.
Keywords
Iodine thiocyanate , Additions to alkenes , correlations , substituent effects
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1854884
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