Title of article
Regioselectivity in Lewis acids catalyzed X–H (O, S, N) insertions of methyl styryldiazoacetate with benzyl alcohol, benzyl thiol, and aniline
Author/Authors
Yue، نويسنده , , Yongli and Wang، نويسنده , , Yuanhua and Hu، نويسنده , , Wenhao، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
3
From page
3975
To page
3977
Abstract
Different from Rh(II) catalysts, X–H (X = O, S, N) insertion of methyl styryldiazoacetate catalyzed by Lewis acids including Cu(I), Cu(II) and Ag(I) complexes occurred at γ-position preferably. Only (E)-isomer was observed in the reactions. This method provides an alternative for the synthesis of γ-hydroxyl or γ-amino acid derivatives.
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1855113
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