Title of article
Rhodium-catalyzed allyl transfer from homoallyl alcohols to acrylate esters via retro-allylation
Author/Authors
Jang، نويسنده , , Minsul and Hayashi، نويسنده , , Sayuri and Hirano، نويسنده , , Koji and Yorimitsu، نويسنده , , Hideki and Oshima، نويسنده , , Koichiro، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
3
From page
4003
To page
4005
Abstract
Retro-allylation of homoallyl alcohols by rhodium catalysts occurs to generate allylrhodium species. Insertion of acrylate esters to the allylrhodiums proceeds to give the corresponding 2,5-hexadienoate esters in situ. Subsequent isomerization or iterative 1,4-addition takes place in the same pots to furnish the corresponding 2,4-hexadienoate esters or triesters in good yields.
Keywords
Allyl transfer , Allylrhodium , carbon–carbon bond cleavage , Retro-allylation
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1855125
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