Title of article
A catalytic, highly stereoselective aldehyde olefination reaction
Author/Authors
Lin، نويسنده , , Yunming and Li، نويسنده , , Zhongtao and Casarotto، نويسنده , , Virginie and Ehrmantraut، نويسنده , , Jessica and Nguyen، نويسنده , , Annie N. Leung، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
4
From page
5531
To page
5534
Abstract
A catalytic aldehyde olefination reaction has been discovered. A Cu(II) complex (5 mol %) derived from a salen-quinine mixed ligand catalyzed the reaction between aldehydes and two molecules of acetyl chloride to produce trans C–C double bonds exclusively. The new catalytic aldehyde alkenation reaction presumably goes through a C-3 acylated β-lactone intermediate that loses one molecule of CO2.
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1855870
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