Title of article
Katsuki–Jacobsen oxidation–epoxidation of α-silyloxy sulfinyl dienes: application to the formal synthesis of (6S,7S,9R,10R)-6,9-epoxynonadec-18-ene-7,10-diol
Author/Authors
de la Pradilla، نويسنده , , Roberto Fernلndez and Castellanos، نويسنده , , Alejandro، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
5
From page
6500
To page
6504
Abstract
The Katsuki–Jacobsen oxidation–epoxidation of acyclic α-silyloxy sulfinyl dienes, followed by acid-promoted cyclization, leads to 2,5-trans sulfonyl dihydrofurans with good selectivities. As an application, the formal synthesis of (6S,7S,9R,10R)-6,9-epoxynonadec-18-ene-7,10-diol is reported.
Keywords
Katsuki–Jacobsen epoxidation , tetrahydrofurans , sulfoxides
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1856407
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