Title of article
A stereoselective total synthesis of (−)-andrachcinidine via an olefin cross-metathesis protocol
Author/Authors
Radha Krishna، نويسنده , , Palakodety and Dayaker، نويسنده , , G.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
4
From page
7279
To page
7282
Abstract
A stereoselective total synthesis of 1-(2S,6R)-6-[(2S)-2-hydroxypentyl]-hexahydro-2-pyridinylacetone, (−)-andrachcinidine is reported. The strategy utilizes olefin cross-metathesis and intramolecular SN2 cyclization as the key steps.
Keywords
Garner’s aldehyde , 1 , Sharpless asymmetric epoxidation , Grubbs’ catalyst , olefin cross-metathesis , Intramolecular SN2 cyclization , Hydroboration , 3-anti Chiral allylation
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1856786
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