Title of article
Asymmetric synthesis of (+)-iso-6-cassine via stereoselective intramolecular amidomercuration
Author/Authors
Singh، نويسنده , , Satwinder and Singh، نويسنده , , Om V. and Han، نويسنده , , Hyunsoo، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
4
From page
8270
To page
8273
Abstract
The first asymmetric synthesis of (+)-iso-6-cassine is described. Lipase-catalyzed resolution, enantioselective Overman rearrangement, and diastereoselective intramolecular amidomercuration were used for the installation of the three stereocenters in (+)-iso-6-cassine, and cross-metathesis was employed for the attachment of the side-chain.
Keywords
2 , Intramolecular amidomercuration , 6-Dialkylpiperidines , 6-Disubstituted 3-piperidinols , 2 , (+)-iso-6-Cassine , double stereodifferentiation
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1857295
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