Title of article
Reaction of selenofenchone with propiolic acid: first instance of Wagner–Meerwein rearrangement in selone
Author/Authors
Okuma، نويسنده , , Kentaro and Mori، نويسنده , , Yuichi and Shigetomi، نويسنده , , Toshiyuki and Tabuchi، نويسنده , , Miki and Shioji، نويسنده , , Kosei and Yokomori، نويسنده , , Yoshinobu، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
3
From page
8311
To page
8313
Abstract
The reaction of selenofenchone (3a) with propiolic acid in refluxing chloroform produced selenodioxenone (4) along with rearranged product (5b), while 5b was obtained in almost quantitative yield under solvent-free conditions. In the presence of Lewis acid, selenofenchone 3a reacted with methyl propiolate to afford corresponding rearranged adduct (7).
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1857313
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