• Title of article

    Reduction of sulfoxides with boranes catalyzed by MoO2Cl2

  • Author/Authors

    Fernandes، نويسنده , , Ana C. and Romمo، نويسنده , , Carlos C.، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2007
  • Pages
    4
  • From page
    9176
  • To page
    9179
  • Abstract
    The first example of an organic reduction with boranes catalyzed by a high valent oxo-complex is reported. The systems catecholborane/MoO2Cl2(H2O)2 (5 mol %) and BH3·THF/MoO2Cl2 (5 mol %) proved to be very efficient for the reduction of sulfoxides to the corresponding sulfides in excellent yields.
  • Keywords
    Reduction , sulfoxides , Dioxomolybdenum dichloride , B–H Activation , Boranes
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2007
  • Journal title
    Tetrahedron Letters
  • Record number

    1857613