Title of article
Reduction of sulfoxides with boranes catalyzed by MoO2Cl2
Author/Authors
Fernandes، نويسنده , , Ana C. and Romمo، نويسنده , , Carlos C.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
4
From page
9176
To page
9179
Abstract
The first example of an organic reduction with boranes catalyzed by a high valent oxo-complex is reported. The systems catecholborane/MoO2Cl2(H2O)2 (5 mol %) and BH3·THF/MoO2Cl2 (5 mol %) proved to be very efficient for the reduction of sulfoxides to the corresponding sulfides in excellent yields.
Keywords
Reduction , sulfoxides , Dioxomolybdenum dichloride , B–H Activation , Boranes
Journal title
Tetrahedron Letters
Serial Year
2007
Journal title
Tetrahedron Letters
Record number
1857613
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