• Title of article

    Indium-mediated vic-diallylation/propargylation of phenacyl bromides: a facile synthesis of 4-arylocta-1,7-dien-4-ol derivatives

  • Author/Authors

    Yadav، نويسنده , , J.S. and Reddy، نويسنده , , B.V. Subba and Biswas، نويسنده , , Swapan Kumar and Sengupta، نويسنده , , Sandip and Vishnumurthy، نويسنده , , P.، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2008
  • Pages
    3
  • From page
    1034
  • To page
    1036
  • Abstract
    Phenacyl bromides undergo smooth vic-diallylation and dipropargylation with allyl and propargyl indium reagents generated in situ from metallic indium and allyl or propargyl bromide to produce 4-arylocta-1,7-dien-4-ol derivatives in good yields. Phenacyl chloride and azide also participated effectively in bis-allylation. Similar results are also obtained from in situ generated allyl or propargyl zinc bromide.
  • Keywords
    indium metal , Phenacyl bromide , vic-diallylation/propargylation , C–C bond formation
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2008
  • Journal title
    Tetrahedron Letters
  • Record number

    1858149