Title of article
Radical chain reactions using THP as a solvent
Author/Authors
Yasuda، نويسنده , , Hiroshi and Uenoyama، نويسنده , , Yoshitaka and Nobuta، نويسنده , , Osamu and Kobayashi، نويسنده , , Shoji and Ryu، نويسنده , , Ilhyong، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2008
Pages
4
From page
367
To page
370
Abstract
THP (tetrahydropyran) has been found to show an excellent stability towards autooxidation, compared with THF. Tributyltin hydride mediated radical cyclization, when conducted in THF as a solvent, suffers from competition of hydrogen abstraction from the solvent, whereas the use of THP resulted in the course to negligible degree. Tributyltin hydride, TTMSS, and hexanethiol mediated radical reactions were carried out successfully using THP as a solvent.
Keywords
Radical reaction , THP , Tin radical , Silicon radical , thiyl radical
Journal title
Tetrahedron Letters
Serial Year
2008
Journal title
Tetrahedron Letters
Record number
1860006
Link To Document