• Title of article

    Intramolecular alkynylogous Mukaiyama aldol type reaction mediated by TBSOTf/NEt3

  • Author/Authors

    Miesch، نويسنده , , Laurence and Rietsch، نويسنده , , Vincent and Welsch، نويسنده , , Tania and Miesch، نويسنده , , Michel، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2008
  • Pages
    3
  • From page
    5053
  • To page
    5055
  • Abstract
    The treatment of propargylic esters tethered to bicyclo[3.2.0]heptanone, 2-methylindanone, 2-methyltetralone, or 2-methylsuberone led to fused tricyclic allenoates by an intramolecular alkynylogous Mukaiyama aldol type reaction promoted by TBSOTf/NEt3, the key intermediates being silylalkynylketene acetals.
  • Keywords
    Allenoate , Alkynylogous , aldol , Lewis acids , Cascade
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2008
  • Journal title
    Tetrahedron Letters
  • Record number

    1860651