Title of article
An extended tetrathiafulvalene redox-ligand incorporating a thiophene spacer
Author/Authors
Trippé، نويسنده , , Gaëlle and Canevet، نويسنده , , David and Le Derf، نويسنده , , Franck and Frere، نويسنده , , Pierre and Sallé، نويسنده , , Marc، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2008
Pages
3
From page
5452
To page
5454
Abstract
An extended tetrathiafulvalene derivative incorporating a thiophene spacer and a fused crown-ether unit has been synthesized. This highly delocalized system exhibits remarkable electrochemical recognition properties for Na+ and Ba2+ as shown by cyclic voltammetry in methylene chloride. This result is attributed to the proximity between the guest metal cation and the positive charge of the oxidized ligand, which is located on the central conjugated thiophenic part.
Keywords
Thiophene , tetrathiafulvalene , Redox-responsive ligand , electrochemical , Crown-ether
Journal title
Tetrahedron Letters
Serial Year
2008
Journal title
Tetrahedron Letters
Record number
1860827
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