Title of article
The Danishefsky pyranone puzzle: an explanation based on the exterior frontier orbital extension model
Author/Authors
Kaneno، نويسنده , , Daisuke and Tomoda، نويسنده , , Shuji، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
4
From page
329
To page
332
Abstract
The unusual facial stereoselection in the hydride reduction of the Danishefsky pyranones (2,3,5,6-tetrahydro-4-pyranones) with L-Selectride (Li-sec-Bu3BH) has been explained based on the exterior frontier orbital extension model (the EFOE model).
Keywords
hydride reduction , L-Selectride , Ab initio MO calculation , Danishefsky pyranone , diastereoselection
Journal title
Tetrahedron Letters
Serial Year
2009
Journal title
Tetrahedron Letters
Record number
1862328
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