Title of article
Incorporation of hexafluorobutyne into furans or phenols via reaction with iron(0) carbene or vinylketene complexes
Author/Authors
Akhani، نويسنده , , Ravish K. and Atiq-ur-Rehman and Schnatter، نويسنده , , Wayne F.K. and Warner، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
3
From page
930
To page
932
Abstract
Reaction of iron(0) carbene complexes with hexafluorobut-2-yne produces 3,4-bis(trifluoromethylated)furans in a process that is favored for electron-rich carbenes. No traces of furannulation or benzannulation are observed with Group 6 Fischer carbenes. Reaction of hexafluorobut-2-yne with a vinylketene iron(0) complex gives a 2,3-bis-trifluoromethylated phenol.
Journal title
Tetrahedron Letters
Serial Year
2009
Journal title
Tetrahedron Letters
Record number
1862723
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