• Title of article

    InX3-catalyzed haloamidation of vinyl arenes: a facile synthesis of α-bromo- and α-fluoroamides

  • Author/Authors

    Yadav، نويسنده , , J.S and Subba Reddy، نويسنده , , B.V. and Narasimha Chary، نويسنده , , D. and Chandrakanth، نويسنده , , D.، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2009
  • Pages
    3
  • From page
    1136
  • To page
    1138
  • Abstract
    A variety of alkenes are converted into the corresponding α-fluoroamides in high yields by selectfluorTM in the presence of 10 mol % of InF3 in nitrile solution. α-Bromoamides are obtained with NBS in the presence of 10 mol % InBr3 under similar conditions. The use of Lewis acid in haloamidation significantly improved the yields and reaction rates.
  • Keywords
    Indium(III) halides , Haloamidation , ?-Fluoroamides , Vinyl arenes
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2009
  • Journal title
    Tetrahedron Letters
  • Record number

    1862832