• Title of article

    Sodium carbonate as a solid-phase reagent for the generation of acetylketene

  • Author/Authors

    Bell، نويسنده , , Kelcey and Sadasivam، نويسنده , , Dhandapani V. and Gudipati، نويسنده , , Indra Reddy and Ji، نويسنده , , Hua and Birney، نويسنده , , David، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2009
  • Pages
    3
  • From page
    1295
  • To page
    1297
  • Abstract
    Reaction of a toluene solution of 3-oxobutanoyl chloride (14) with Na2CO3 in the presence of a catalytic amount of triethylamine at −78 °C generates a solution of acetylketene (2), the dimer of which was isolated. Acetylketene (2) was trapped with 2-propanone, 2-propanol, and ethyl vinyl ether.
  • Journal title
    Tetrahedron Letters
  • Serial Year
    2009
  • Journal title
    Tetrahedron Letters
  • Record number

    1862905