Title of article
A conformational study of [3.3](3,5)pyridinophane
Author/Authors
Shibahara، نويسنده , , Masahiko and Watanabe، نويسنده , , Motonori and Suenaga، نويسنده , , Masahiko and Ideta، نويسنده , , Keiko and Matsumoto، نويسنده , , Taisuke and Shinmyozu، نويسنده , , Teruo، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
5
From page
1340
To page
1344
Abstract
A variable temperature 1H NMR study of the [3.3](3,5)pyridinophane indicated that the syn(chair/chair) is more stable than syn(chair/boat) by 0.2 kcal/mol in solution, whereas the trimethylene bridges show disorder even at −150 °C in the solid state. A transition state search by ab initio MO calculations suggested two competitive conformational changes for syn(chair/chair)–syn(chair/boat) conversion via a bridge wobble or a ring inversion in the [3.3](3,5)pyridinophane.
Journal title
Tetrahedron Letters
Serial Year
2009
Journal title
Tetrahedron Letters
Record number
1862927
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