Title of article
A biomimetic type expedient approach to the tricyclic core of xyloketals. Application to a short, stereocontrolled synthesis of alboatrin and a remarkable epi to natural isomerisation
Author/Authors
Sarkar، نويسنده , , Debayan and Ghosh، نويسنده , , Subrata and Venkateswaran، نويسنده , , Ramanathapuram V. Venkateswaran، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
4
From page
1431
To page
1434
Abstract
An expedient synthesis of the linear tetrahydrofurano benzopyran ring system of xyloketals is described involving an ortho ester Claisen rearrangement and an intramolecular cationic cyclisation. This strategy was applied for a short, stereocontrolled and high yield synthesis of the phytotoxic metabolite alboatrin.
Keywords
Ortho ester Claisen rearrangement , Intramolecular cationic cyclisation , Alboatrin , Tetrahydrofurano benzopyran , Xyloketals
Journal title
Tetrahedron Letters
Serial Year
2009
Journal title
Tetrahedron Letters
Record number
1862970
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