Title of article
Catalytic monoalkylation of 1,2-diols
Author/Authors
Maki، نويسنده , , Toshihide and Ushijima، نويسنده , , Nobuto and Matsumura، نويسنده , , Yoshihiro and Onomura، نويسنده , , Osamu، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
3
From page
1466
To page
1468
Abstract
A catalytic monoalkylation of 1,2-diols by using a weak base has been developed. Copper(II) dichloride and boronic acids are effective catalysts for activating 1,2-diols in the presence of potassium carbonate as a base. Various 1,2-diols were selectively monoalkylated with allyl-, benzyl- and alkyl- halides in DMF by choosing a suitable catalyst for each 1,2-diols.
Keywords
Diol , allylation , Alkylation , benzylation , Lewis acid
Journal title
Tetrahedron Letters
Serial Year
2009
Journal title
Tetrahedron Letters
Record number
1862989
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