Title of article
Carbocation rearrangements in aspernomine biosynthesis
Author/Authors
Ho، نويسنده , , Gregory A. and Nouri، نويسنده , , Dustin H. and Tantillo، نويسنده , , Dean J.، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
4
From page
1578
To page
1581
Abstract
Quantum chemical calculations (B3LYP/6-31G(d)) on carbocation rearrangements that are proposed to occur in the biosynthesis of aspernomine are described. Based on these calculations, a pathway involving a concerted but asynchronous [4+2] cycloaddition that avoids the formation of a secondary carbocation is proposed for small model systems.
Journal title
Tetrahedron Letters
Serial Year
2009
Journal title
Tetrahedron Letters
Record number
1863055
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