Title of article
Tetrabutylammonium phenoxide induced reaction of silyl nucleophiles
Author/Authors
Capperucci، نويسنده , , Antonella and Tiberi، نويسنده , , Caterina and Pollicino، نويسنده , , Salvatore and Degl’Innocenti، نويسنده , , Alessandro، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
3
From page
2808
To page
2810
Abstract
Reaction of silyl dithiolanes with electrophiles can be efficiently promoted by catalytic amounts of tetrabutylammonium phenoxide (PhONn–Bu4), leading to a convenient access to functionalized dithiolanes. PhONn–Bu4 proved effective also in promoting reactions of silylated sulfides such as PhSTMS and HMDST as well as silylated selenides such as PhSeTMS and HMDSS toward epoxides. The present reactivity is also observed on using ILs as reaction media.
Keywords
Selenosilanes , Silylsulfides , Silyldithiolanes , Phenoxide ion
Journal title
Tetrahedron Letters
Serial Year
2009
Journal title
Tetrahedron Letters
Record number
1863970
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