Title of article
Copper-catalyzed desymmetrization of oxabenzonorbornadienes with aluminum reagents
Author/Authors
Millet، نويسنده , , Renaud and Bernardez، نويسنده , , Tania and Palais، نويسنده , , Laëtitia and Alexakis، نويسنده , , Alexandre، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
4
From page
3474
To page
3477
Abstract
The desymmetrization of oxabenzonorbornadienes with aluminum reagents and SimplePhos as chiral ligand is described. The corresponding homoallylic alcohols are obtained in high yield, diastereoselectivity, and enantiomeric excess. Furthermore the first anti enantioselective desymmetrization with aromatic nucleophiles is reported.
Journal title
Tetrahedron Letters
Serial Year
2009
Journal title
Tetrahedron Letters
Record number
1864449
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